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IIHR Researchers Find Toxic PCBs

Posted on December 5th, 2011

Andres Martinez, PhD
Postdoctoral Research Scholar
Civil & Environmental Engineering

Faculty mentor: Keri Hornbuckle
Hometown: Valdivia, Chile

IIHR Postdoc Andres Martinez.

IIHR Postdoc Andres Martinez.

Andres Martinez never loses sight of his reason for doing academic research.

When his paper is rejected by journal reviewers, this postdoctoral scholar in civil and environmental engineering accepts the critique and takes the necessary steps to move closer to achieving his ultimate goal.

“He fully understands that the goal is getting the papers published,” says Keri Hornbuckle, IIHR research engineer, professor of civil and environmental engineering, and Martinez’s mentor. “All the work we do doesn’t count until somebody else reads it.”

One of Martinez’s rejected papers recently evolved into a “significant” piece of research.

Martinez and Hornbuckle found high levels of toxic polychlorinated biphenyls (PCBs) in the deep sediments lining the Indiana Harbor and Ship Canal (IHSC) in East Chicago, Ind. They say the discovery is cause for concern because the IHSC is scheduled to be dredged in spring 2012 to maintain proper depth for ship traffic in this heavily industrialized area of southern Lake Michigan.

The study, published online in the journal Chemosphere on Sept. 6, builds upon a previous UI study that found the release of PCBs from the sediment floor to the water above, and then, to the air. This time, scientists drilled down into the floor of the canal and discovered that the concentration of PCBs buried within the sediment is even higher.

“We found that the deeper you go, the more toxic it is,” says Martinez, lead author of the study. “Dredging the IHSC has the potential to expose these more toxic sediments.”

Martinez credits Hornbuckle for providing guidance about the steps necessary in achieving publication.

“Keri always has time, and the discussion is really good between her and her students,” Martinez says. “She has more knowledge about PCBs in the air, so the sediment thing has been challenging for both of us.”

PCBs can enter the human body by eating or drinking contaminated food, through the air we breathe, or by skin contact. According to the Environmental Protection Agency (EPA), these compounds have been shown to cause cancer, along with a variety of other adverse health effects on the body’s immune, reproductive, nervous, and endocrine systems.

“This finding demonstrates that the concentration of toxic chemicals below the surface of the canal floor is quite high,” says Hornbuckle, co-author of the study. “We need to get this information out, because the level of pollutants underneath the sediment has never been reported.”

PCBs were widely used as coolants in electrical transformers and in a wide variety of products, ranging from waterproofing compounds to paints and pesticides. They were manufactured from 1929 until they were banned in 1979 due to their toxicity and lingering effects on the environment.

To calculate accurate estimates of the amount and relative distribution of PCBs in the deep sediment of the IHSC, UI researchers employed a submersible vibro-coring system and collected two core samples.

In a statistical analysis, Martinez determined that sediments collected far from Lake Michigan and the main canal, where there is less vessel traffic, had PCB concentrations higher than 50 parts per million (ppm), which qualifies as hazardous waste according to EPA standards. At those levels, the IHSC could be designated a Superfund Site. Superfund is a federal effort to clean up abandoned hazardous waste sites.

The IHSC is an active canal system that supports large vessels. But to remain viable for industrial shipping, the U.S. Army Corps of Engineers, Chicago District, plans to begin a long-term dredging project to restore adequate navigational depth.

Hornbuckle and Martinez recommend that the PCB concentrations in the sediment be considered in the dredging strategy to reduce the potential release of PCBs into the environment.

“They need to dredge it, but I think they need to dredge it all,” Hornbuckle says. “If you were going to dredge it all, you would figure out where all the pollutants are and then you would remove them and move them somewhere safe. They don’t intend to dredge it all, because that would be much more expensive and disruptive to this very active harbor.”

Researchers acknowledge that the Army Corps of Engineers may not dredge deep enough to expose the highly toxic PCBs. Now that they’ve identified the presence of toxic PCBs in the deep sediment, the next step is to try to predict what will happen if the new sediment is exposed.

Martinez is attempting to answer this question by using a passive sampler that pulls PCBs out of the pore waters, which occupy the spaces between sediment particles.

“He’s using a very thin piece of glass that is coated with a polymer. He puts that into the sediment to pull the PCBs out of the pore waters,” Hornbuckle says. “Before, we would just take a bulk of mud and extract it that way. Now, he is using a much more refined technique to measure only the dissolved PSBs that are in the pore water. There are very few groups that are trying to do this. The reviewers recognized that is the number we needed.”

For more about UI postdoctoral scholars and fellows, contact:
University of Iowa Office of Postdoctoral Scholars
Anne-Marie Ericson, Program Coordinator (postdoc-office@uiowa.edu)
Web: postdoc.grad.uiowa.edu
(Postdocs @ Iowa series written by John Riehl, Graduate College)
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